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RAS Chemistry & Material ScienceХимическая физика Advances in Chemical Physics

  • ISSN (Print) 0207-401X
  • ISSN (Online) 3034-6126

Effect of organic corrosion inhibitors on the kinetics of the cathodic hydrogen evolution reaction on steel in a sulfuric acid solution

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PII
10.31857/S0207401X24010033-1
DOI
10.31857/S0207401X24010033
Publication type
Article
Status
Published
Authors
Ya. G. Avdeev
  • Affiliation: A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Volume/ Edition
Volume 43 / Issue number 1
Pages
24-38
Abstract
The kinetics of hydrogen cathodic reduction on low-carbon steel in a sulfuric acid solution containing a mixture of quaternary ammonium salts (catamine AB) and 3-substituted 1,2,4-triazole (IFKhAN-92 inhibitor) has been studied. The main rate constants of the stages of evolution of gaseous hydrogen and the permetion of hydrogen atoms into the metal are determined. It is shown that these substances reduce the reaction rate of the discharge of H+ ions, change the ratio between the concentrations of H atoms on the surface and in the phase of the metal, and, as a result, reduce the amount of hydrogen absorbed by steel. The most effective inhibitor of corrosion and hydrogenation of steel is IFKhAN-92, due to the formation of a polymolecular protective layer of the inhibitor on the metal surface. The data of X-ray photoelectron spectroscopy of the steel surface show that the protective layer has a thickness of no more than 4 nm and consists of IFKhAN-92 molecules associated with the steel surface by chemical interaction, and inside the layer by physical interaction.
Keywords
фотоиндуцированный перенос заряда неравновесные реакции макро-молекулярные системы недебаевская полярная среда
Date of publication
14.09.2025
Year of publication
2025
Number of purchasers
0
Views
2

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