RAS Chemistry & Material ScienceХимическая физика Advances in Chemical Physics

  • ISSN (Print) 0207-401X
  • ISSN (Online) 3034-6126

Reaction operator in the main equation of spin chemistry

PII
10.31857/S0207401X24020016-1
DOI
10.31857/S0207401X24020016
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 43 / Issue number 2
Pages
3-8
Abstract
In our previous works, using an exactly solvable model as an example, we demonstrated the validity of the reaction operator in the basic equation of spin chemistry. However, in these works, only recombination from the singlet state was considered. Although the general relations allowed us to consider the general case. In the present paper, such a general case is analyzed. The radical pair comes into contact in a mixed singlet-triplet state, and recombination proceeds from both the singlet and triplet states. The result obtained fully corresponds to the basic equation of spin chemistry.
Keywords
синглет-триплетные переходы радикальная пара рекомбинация матрица плотности проекционный оператор спин-гамильтониан
Date of publication
14.09.2025
Year of publication
2025
Number of purchasers
0
Views
2

References

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