- PII
- 10.31857/S0207401X24100089-1
- DOI
- 10.31857/S0207401X24100089
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 43 / Issue number 10
- Pages
- 89-99
- Abstract
- The paper considers data on winter monitoring of the ionic composition of aerosol particles and small gas components in the surface atmosphere of Antwerp and Beijing. According to the results of their comparison, it is shown that the rapid accumulation of NO3- over Beijing in haze particles is triggered by a liquid-phase catalytic reaction of sulfate formation involving Mn/Fe ions, which proceeds in a fast degenerate branched mode. The cycle of these transformations is accompanied by the associated production of nitrate radicals in the particles. Their release into the gas phase leads to an increase in the concentration of N2O5 molecules, and a rapid accumulation of nitrates. The coupling of the catalytic (petrochemical) conversion of sulfur dioxide into sulfates and the nitrate production process over Beijing thus plays a crucial role in the formation of the mineral composition of haze particles in the atmosphere.
- Keywords
- аэрозольная дымка нитраты и сульфаты катализ вырождено-разветвленный режим ионы переходных металлов
- Date of publication
- 14.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 3
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