RAS Chemistry & Material ScienceХимическая физика Advances in Chemical Physics

  • ISSN (Print) 0207-401X
  • ISSN (Online) 3034-6126

Interaction of sodium atoms with molecular nitrogen in the upper atmosphere of the earth

PII
10.31857/S0207401X24100094-1
DOI
10.31857/S0207401X24100094
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 43 / Issue number 10
Pages
100-114
Abstract
In recent years numerous satellite data on the yellow glow of the sodium layer (located at an altitude of 85–95 km from the Earth’s surface) have become available. Studies of optical activity at sodium D-line frequencies are necessary for a better understanding of the plasma-chemical processes occurring in the mesosphere. It should be taken into account that these processes occur in a neutral environment, where the molecular nitrogen is general component. In this work the analytical numerical expressions for the elements of 3´3 matrix of interaction between Na(2Pj) and N2(X 1Sg+) and interaction potential between Na(2S1/2) and N2(X 1Sg+) were obtained at medium and large interpartical distances that determine radiation lines collisional broadening. The exchange, quadrupole–quadrupole, dispersion, and spin–orbit interactions were taken into account. Exchange interaction between the valence Na electron and N2(X 1Sg+) molecule was described by the local Hellman pseudopotential. The effect of the overlap between Na(2S1/2, 2Pj) and N2(X 1Sg+) electron densities was taken into account evaluating long-range quadrupole–quadrupole and dispersion interactions.
Keywords
натриевый слой уширение симметрия электронная плотность обменное взаимодействие квадруполь-квадрупольное взаимодействие дисперсионное взаимодействие
Date of publication
14.09.2025
Year of publication
2025
Number of purchasers
0
Views
4

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