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RAS Chemistry & Material ScienceХимическая физика Advances in Chemical Physics

  • ISSN (Print) 0207-401X
  • ISSN (Online) 3034-6126

Influence of europium chelate on the chemiluminescence kinetics during free-radical oxidation of lipid samples of vegetable origin

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PII
10.31857/S0207401X24110072-1
DOI
10.31857/S0207401X24110072
Publication type
Article
Status
Published
Authors
V. V. Naumov
  • Affiliation:
    Emanuel Institute of Biochemical Physics, Russian Academy of Sciences
    Moscow Institute of Physics and Technology (National Research University)
Volume/ Edition
Volume 43 / Issue number 11
Pages
54-61
Abstract
The chemically inert luminophore, chemiluminescence enhancer 1,10-phenanthroline-tris(thenoyl-trifluoroacetonate) of trivalent europium, increases the intensity of the light emission by an order of magnitude during the initiated oxidation of lipid samples of vegetable origin (sunflower oil). The introduction of the light enhance r into the chemiluminescence system leads to altering the kinetic profile, removing characteristic peaks on the kinetic curves at the end of the induction period of the oxidation process, but without changing the induction period itself. With the mathematical computer modeling based on a kinetic scheme of 23 elementary reactions, it was shown that the observed kinetic behavior can be rationalized by a disproportionate increase in quantum yields of chemiluminescence derived from different electronically excited products (light emitters) formed during the oxidation process.
Keywords
хемилюминесценция 1,10-фенантролин-трис(теноил-трифторацетонат) трехвалентного европия растительные липиды свободно-радикальное окисление кинетика
Date of publication
14.09.2025
Year of publication
2025
Number of purchasers
0
Views
3

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