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RAS Chemistry & Material ScienceХимическая физика Advances in Chemical Physics

  • ISSN (Print) 0207-401X
  • ISSN (Online) 3034-6126

Photogeneration of charge carriers in organic solar cells. The role of nonequilibrium states for electrons and holes

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PII
10.31857/S0207401X24120071-1
DOI
10.31857/S0207401X24120071
Publication type
Article
Status
Published
Authors
L. V. Lukin
  • Affiliation: Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Volume/ Edition
Volume 43 / Issue number 12
Pages
66-83
Abstract
The aim of this study is to consider a photogeneration of charge carriers in nano-structured blends of the donor (D) and acceptor (A) materials. Upon optical excitation photons absorbed in one of these materials produce intramolecular excitons which can diffuse to the D–A interface and form at the interface the interfacial CT states. The interfacial CT state dissociates into a geminate pair of the non-equilibrium mobile electron and hole. In the present study, an empirical model describing thermalization of the non-equilibrium charges within the Coulomb well is proposed. Efficiency of the interfacial CT state dissociation into a pair of free charges is found as a function of the electric field applied, effective temperature and diffusion length of non-equilibrium electron-hole pairs.
Keywords
фотоионизация органическая фотовольтаика разделение зарядов
Date of publication
15.09.2025
Year of publication
2025
Number of purchasers
0
Views
3

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