RAS Chemistry & Material ScienceХимическая физика Advances in Chemical Physics

  • ISSN (Print) 0207-401X
  • ISSN (Online) 3034-6126

Magnetic aerogels based on reduced graphite oxide – sorbents of the carcinogenic compound K2Cr2O7

PII
10.31857/S0207401X24120099-1
DOI
10.31857/S0207401X24120099
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 43 / Issue number 12
Pages
95-105
Abstract
Nanocomposites based on graphite oxide airgel and superparamagnetic iron oxide nanoparticles (rGO ⋅ Fe3O4) are able to sorb potassium dichromate from aqueous solutions. The superparamagnetic nature of the composite makes it possible to extract it after the completion of the sorption process from the pollutant solution using an external magnetic field. The dependence of the degree of sorption of potassium dichromate by aerogels of the composition rGO ⋅ Fe3O4 on the mass of the sorbent, acidity, and temperature of the medium was studied. It has been shown that in order to increase the degree of potassium dichromate sorption by the rGO ⋅ Fe3O4 magnetic airgel, the process is best carried out at room temperature in media with low pH values. The results obtained make it possible to propose airgels based on graphite oxide and rGO ⋅ Fe3O4 iron oxide nanoparticles as environmentally friendly sorbents for water purification from the carcinogenic substance potassium dichromate. The proposed materials after the end of the sorption process can be completely removed from the reaction medium using an external magnetic field, thereby preventing their action as pollutants. It is important to note that the described 3D structures based on graphite oxide and nanoparticles of superparamagnetic iron oxide Fe3O4 are of practical importance for the treatment of wastewater from enterprises using an oxidative method for removing phenols, cresols, and cyan-containing substances from impurities using potassium dichromate and sulfuric acid.
Keywords
восстановленный оксид графита магнитные наночастицы сорбция дихромат калия
Date of publication
14.09.2025
Year of publication
2025
Number of purchasers
0
Views
4

References

  1. 1. Нескоромная Е.А., Бабкин А.В., Захарченко Е.А. и др. // Хим. физика. 2023. T. 42. № 7. С. 79.
  2. 2. Brodie B.C. // Phil. Trans. R. Soc. Lond. 1859. V. 149. P. 249.
  3. 3. Gao H., Duan H. // Biosens. Bioelectron. 2015. V. 65 P. 404.
  4. 4. Hummers W.S., Offeman R.E. // J. Amer. Chem. Soc. 1958. V. 80. № 6. P. 1339.
  5. 5. Marcano D.C., Kosynkin D.V., Berlin J.M. et al. // ACS Nano. 2010. V. 4. № 8. P. 4806.
  6. 6. Chen W., Yan L. // Nanoscale. 2011. V. 3. P. 3132.
  7. 7. Kondratowicz I., Żelechowska K., Nadolska M. et al. // Colloids Surf., A. 2017. V. 528. P. 65.
  8. 8. Иони Ю.В., Воронов В.В., Наумкин А.В. и др. // ЖНХ. 2015. Т. 60. № 6. С. 783.
  9. 9. Ioni Yu., Buslaeva E., Gubin S. // Mater. Today. V. 3. 2016. P. 209.
  10. 10. Magdalena A.G., Silva I.M.B., Marques R.F.C. et al. // J. Phys. Chem. Solids. 2018. V. 113. P. 5.
  11. 11. Zhao D., Zhang Q., Xuan H. al. // J. Colloid Interface Sci. 2017. V. 506. P. 300.
  12. 12. Yang Y., Zhao Y., Sun Sh. et al. // Materials Res. Bull. 2016. V. 73. P. 401.
  13. 13. Ren M., Yang M., Liu W. et al. // Electrochim. Acta. 2016. V. 194. P. 219.
  14. 14. Fana J.-P., Zhenga B., Qina Y. et al. // Appl. Surf. Sci. 2016. V. 364. P. 332.
  15. 15. Li Y., Zhang R., Tian X. et al. // Ibid. 2016. V. 369. P. 11.
  16. 16. Wang Y., Jin Y., Zhao Ch. et al. // Ibid. 2018. V. 458. P. 1035.
  17. 17. Othman N.H., Alias N.H., Shahruddin M.Z. et al. // J. Environ. Chem. Engin. 2018. V. 6. P. 2803.
  18. 18. Mishra Sh., Yadav A., Verma N. // Chem. Engin. J. 2017. V. 326. P. 987.
  19. 19. Dahaghin Z., Mousavi H.Z., Sajjadi S.M. // J. Mol. Liq. 2017. V. 231. P. 386.
  20. 20. Zhao D., Zhang Q., Xuan H. et al. // Appl. Surf. Sci. 2018. V. 444. P. 691.
  21. 21. Бабкин А.В., Нескоромная Е.А., Бураков А.Е., Буракова И.В. // Вест. ТГТУ. 2018. Т. 24. № 1. С. 79.
QR
Translate

Индексирование

Scopus

Scopus

Scopus

Crossref

Scopus

Higher Attestation Commission

At the Ministry of Education and Science of the Russian Federation

Scopus

Scientific Electronic Library