- PII
- S3034612625110095-1
- DOI
- 10.7868/S3034612625110095
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 44 / Issue number 11
- Pages
- 76-88
- Abstract
- Self-healing polyurethane block copolymers with a test content of the "hard" block of 60 wt.% based on chain extenders obtained by the reversible reaction between furfuryl alcohol and bismaleimides containing fragments with different donor-acceptor properties have been synthesized and studied for the first time. The degree of influence of the obtained chain extenders and the selected mass content of the "hard" block on the structural features of the synthesized polymers have been studied using IR-spectroscopy. Temperature transitions and the cyclic nature of the direct and retro- reactions have been determined using differential scanning calorimetry. The mechanical properties of the materials have been studied using dynamometric analysis of the original and restored samples of polyurethane block copolymers, and a quantitative assessment of the self-healing efficiency of Young's modulus and tensile strength has been carried out. Visual assessment of the self-healing ability of the materials was carried out using scanning electron microscopy. It was demonstrated that the approach to the development of self-healing polyurethane materials proposed by the authors of the article made it possible to obtain materials with both excellent mechanical properties (Young's modulus ~1124–1465 MPa, tensile strength ~33–38 MPa) and the efficiency of their recovery (η ~ 85–90% and η ~ 92–127%), which is significantly higher than similar values for most known self-healing polyurethanes. It was analyzed that the outstanding elastic-strength properties and the efficiency of recovery of the developed polyurethane materials are provided by the formation of a large number of intermolecular spatial physical crosslinks and increased availability of furan and maleimide groups for the process of thermally induced self-healing due to their concentration in one phase.
- Keywords
- полиуретаны блоксополимеры самовосстановление реакция Дильса–Альдера
- Date of publication
- 20.05.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 27
References
- 1. Петрова Т.В., Третьяков И.В., Солодилов В.И. // Хим. физика. 2023. Т. 42. № 1. C. 50. https://doi.org/10.31857/S0207401X23010089
- 2. Petrova T.V., Tretyakov I.V., Solodilov V.I. // Russ. J. Phys. Chem. B. 2023. V. 17. № 1. P. 177. https://doi.org/10.1134/S1990793123010086
- 3. Кириллов В.Е., Юрков Г.Ю., Коробов М.С., Воронов А.С., Солодилов В.И. и др. // Хим. физика. 2023. Т. 42. № 11. C. 39. https://doi.org/10.31857/S0207401X23110043
- 4. Kirillov V.E., Yurkov G.Yu., Korobov M.S., Voronov A.S., Solodilov V.I. et al. // Russ. J. Phys. Chem. B. 2023. V. 17. № 6. P. 1346. https://doi.org/10.1134/S1990793123060040
- 5. Вяткина М.А., Горбаткина Ю.А., Петрова Т.В., Солодилов В.И. // Хим. физика. 2023. Т. 42. № 11. C. 16. https://doi.org/10.31857/S0207401X23110110
- 6. Vyatkina M.A., Gorbatkina Yu.A., Petrova T.V., Solodilov V.I. // Russ. J. Phys. Chem. B. 2023. V. 17. № 6. P. 1323. https://doi.org/10.1134/S1990793123060118
- 7. Воробьев А.О., Кульбакин Д.Е., Чистяков С.Г. и др. // Хим. физика. 2023. Т. 42. № 11. C. 9. https://doi.org/10.31857/S0207401X23110109
- 8. Vorobyev A.O., Kulbakin D.E., Chistyakov S.G., et al.// Russ. J. Phys. Chem. B. 2023. V. 17. № 6. P. 1316. https://doi.org/10.1134/S1990793123060106
- 9. An Z.W., Xue R., Ye K. et al. // Nanoscale. 2023. V. 15. № 16. P. 6505. https://doi.org/10.1039/D2NR07110J
- 10. Zheng B., Liu T., Liu J. et al. // Composites, Part B. 2023.V. 257. P. 110697. https://doi.org/10.1016/j.compositesb.2023.110697
- 11. Cheng B.X., Lu C.C., Li Q. et al. // J. Polym. Environ. 2022. V. 30. № 12. P. 5252. https://doi.org/10.1007/s10924-022-02586-z
- 12. Chen L., Dai Z., Lou W. et al. // J. Appl. Polym. Sci. 2022. V. 139. № 30. Article 52694. https://doi.org/10.1002/app.52694
- 13. Li P.X., Zhang Z.Y., Cui J.Y., et al. // Langmuir. 2024. V. 40. № 23. P. 12250. https://doi.org/10.1021/acs.langmuir.4c01363
- 14. Platonova E.O., Ponomareva P.F., Tretyakov I.V. et al. // Polym. Sci. Ser. C. Sel. Top. 2024. V. 66. № 1. P. 160. https://doi.org/10.1134/S1811238224600228
- 15. Li Z.F., Xu C.M., Yin S.M., Wen L.R. // Spectrosc. Spect. Anal. (China). 2002. V. 22. P. 774.
- 16. Wolinska-Grabczyk A., Kaczmarczyk B., Jankowski A. // Pol. J. Chem. Technol. 2008. V.10. № 4. P. 53. https://doi.org/10.2478/v10026-008-0049-8
- 17. Feng L., Yu Z., Bian Y., Lu J., Shi X., Chai C. // Polymer. 2017. V. 124. P.48. https://doi.org/10.1016/j.polymer.2017.07.049
- 18. Xiao S., Hossain M.M., Liu P., Wang H., Hu F. et al. // Mater. Des. 2017. V. 132. P. 419. https://doi.org/10.1016/j.matdes.2017.07.016
- 19. Functional Polymers / Eds. Abu Jafar M. et al. Cham, Switzerland: Springer Int. Publ., 2018. P. 225. https://doi.org/10.1007/978-3-319-92067-2
- 20. Guazzini T., Bronco S., Carignani E. et al. // Eur. Polym. J. 2019. V. 114. P. 298. https://doi.org/10.1016/j.eurpolymj. 2019.02.023
- 21. Krol P. // Prog. Mater. Sci. 2007. V. 52. № 6. P. 915. https://doi.org/10.1016/j.pmatsci.2006.11.001
- 22. Zakharova D.V., Lok’yaeva Z.A., Pavlov A.A., Polezhaev A.V. // Key Eng. Mater. 2021. V. 899. P. 628. https://doi.org/10.4028/www.scientific.net/kem.899.628
- 23. Platonova E.O., Ponomareva P.F., Lokiaeva Z.A. et al. // Polymers. 2022. V. 14. № 24. P. 5394. https://doi.org/10.3390/polym14245394
- 24. Yan Q., Zhou M., Fu H. // J. Mater. Chem. C. 2020. V. 8. № 23. P. 7772. https://doi.org/10.1039/C9TC06765E
- 25. Zhou X., Wang H., Li S. et al. // Eur. Polym. J. 2021. V. 159. P. 110769. https://doi.org/10.1016/j.eurpolymj.2021.110769
- 26. Syed E.A. Master Thesis. Loughborough, UK: Loughborough University, 2021. V. 1. https://doi.org/10.26174/thesis.lboro.15035103
- 27. Zhang C. et al. // J. Mol. Model. 2010. V. 16. P. 1391. https://doi.org/10.1007/s00894-010-0645-4
- 28. Luo W. et al. // Macromolecules. 1997. V. 30. № 15. P. 4405. https://doi.org/10.1021/ma951386e
- 29. Platonova E. et al. // Polymers. 2021. V. 13. № 12. Article 1935. https://doi.org/10.2478/v10026-008-0049-8
- 30. Bednarczyk P. et.al. // J. Appl. Polym. Sci. 2023. V. 140. № 32. Article 54266. https://doi.org/10.1002/app.54266
- 31. Lokiaeva Z.A., Soboleva J.A., Zakharova D.V., Storozhuk I.P. // E3S Web Conferences. 2023. V. 413. Article 02036. https://doi.org/10.1051/e3sconf/202341302036
- 32. Venkatesh D., Jaisankar V. // Mater. Today: Proc. 2019. V. 14. Part 2. P. 482. https://doi.org/10.1016/j.matpr.2019.04.171
- 33. Petrova T.V., Tretyakov I.V., Kireynov A.V. et al. // Appl. Sci. 2023. V. 13. Article 6557. https://doi.org/10.3390/app13116557
- 34. Behera P., Raut S., Mondal P. et al. // ACS Appl. Polym. Mater. 2021. V. 3. № 2. P. 847. https://doi.org/10.1021/acsapm.0c01179
- 35. Jiang H., Yan T., Cheng M. et al. // Mater. Horiz. 2025. V. 12. № 2. P.599. https://doi.org/10.1039/D4MH01129E
